TC4合金表面双阴极等离子溅射沉积糖心产精国品免费入口*完整版的摩擦磨损性能
Friction and Wear Properties of Double Cathode Plasma Sputtering Deposited NbTiN2
Coating on TC4 Alloy Surface
摘 要
采用双阴极等离子溅射沉积技术在TC4合金表面制备了糖心产精国品免费入口*完整版,研究了涂层的物相组成、微观形貌、糖心产精国品免费入口*完整版、与基体的结合情况以及摩擦磨损性能。结果表明:糖心产精国品免费入口*完整版具有很强的(220)晶面择优取向特点;涂层表面质量良好,无明显缺陷,厚度约为10 μm,平均糖心产精国品免费入口*完整版为2 478.46 HV,约为基体的6倍,涂层划痕试验的临界载荷为68.5 N,涂层与基体结合良好;在2~5 N载荷、室温下涂层的摩擦因数低于基体,磨痕比基体窄,磨损率比基体低一个数量级,涂层的主要磨损机制是疲劳磨损;500℃下涂层的摩擦因数较室温高,磨痕更窄更浅,磨损率较低,磨损机制为黏着磨损和氧化磨损,涂层表现出更好的糖心产精国品免费入口*完整版。
糖心产精国品免费入口*完整版
糖心产精国品免费入口*完整版
磨损率
NbTiN2
coating
糖心产精国品免费入口*完整版
糖心产精国品免费入口*完整版
wear rate
Abstract
NbTiN2 coating was prepared on TC4 alloy surface by dual cathode plasma sputtering deposition. The phase composition, microstructure, 糖心产精国品免费入口*完整版, adhesion to matrix and friction and wear properties of the coating were studied. The results show that the NbTiN2 coating had strong (220) preferred orientation. The coating had good surface quality, no obvious defects and a thickness of about 10 μm. The average 糖心产精国品免费入口*完整版 of the coating was 2 478.46 HV, about 6 times that of the matrix, and the critical load of coating in scratch test was 68.5 N, indicating that the coating was well combined with the matrix. The friction coefficient of the coating was lower than that of the matrix under the load of 2-5 N at room temperature; the wear scar was narrower than that of the matrix, and the 糖心产精国品免费入口*完整版of the coating was one order of magnitude lower than that of the matrix; the main wear mechanism of the coating was fatigue wear. At 500 ℃, the friction coefficient was higher than that at room temperature, and the wear scar of the coating was narrower and shallower; the 糖心产精国品免费入口*完整版was lower, and the wear mechanism was adhesive wear and oxidation wear, indicating the coating had better 糖心产精国品免费入口*完整版.
中图分类号 TG174.445DOI 10.11973/jxgccl202209006
所属栏目 材料性能及应用
基金项目 武汉工程大学研究生教育创新基金资助项目(CX2020060)
收稿日期 2021/8/19
修改稿日期 2022/7/8
网络出版日期
作者单位
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糖心产精国品免费入口*完整版教授
备注糖心产精国品免费入口*完整版(1972-),女,湖北武汉人,副教授,博士
引用该论文: SHI Kunyu,ZHUANG Chenqi,WU Weijin,ZHANG Bo,YU Chuanhao. Friction and Wear Properties of Double Cathode Plasma Sputtering Deposited NbTiN2 Coating on TC4 Alloy Surface[J]. Materials for mechancial engineering, 2022, 46(9): 34～39
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参考文献
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【2】 余鹏程,刘秀波,陆小龙,等.Ti6Al4V合金表面激光熔覆复合涂层的高温摩擦学性能研究[J].摩擦学学报,2015,35(6):737-745. YU P C,LIU X B,LU X L,et al.High-temperature tribological properties of laser clad composite coatings on Ti6Al4V alloy[J].Tribology,2015,35(6):737-745.
【3】 BUDINSKI K G.Tribological properties of titanium alloys[J].Wear,1991,151(2):203-217.
【4】 TERAO N.Structure des carbures de niobium[J].Japanese Journal of Applied Physics,1964,3(2):104-111.
【5】 LÉVY F,HONES P,SCHMID P E,et al.Electronic states and mechanical properties in transition metal nitrides[J].Surface and Coatings Technology,1999,120/121:284-290.
【6】 MAKISE K,TERAI H,TAKEDA M,et al.Characterization of NbTiN thin films deposited on various substrates[J].IEEE Transactions on Applied Superconductivity,2011,21(3):139-142.
【7】 VANCOILLE E,CELIS J P,ROOS J R.Mechanical properties of heat treated and worn PVD TiN,(Ti,Al)N,(Ti,Nb)N and Ti(C,N) coatings as measured by nanoindentation[J].Thin Solid Films,1993,224(2):168-176.
【8】 SERRO A P,COMPLETO C,COLAÇO R,et al.A comparative study of titanium nitrides,TiN,TiNbN and TiCN,as coatings for biomedical applications[J].Surface and Coatings Technology,2009,203(24):3701-3707.
【9】 THULL R.Corrosion behavior of dental alloys coated with titanium niobium oxinitride[J].Deutsche Zahnarztliche Zeitschrift,1991,46(11):712-717.
【10】 GISPERT M P,SERRO A P,COLAÇO R,et al.Wear of ceramic coated metal-on-metal bearings used for hip replacement[J].Wear,2007,263(7/8/9/10/11/12):1060-1065.
【11】 JOSHI P.Tribological Testing,Analysis and Characterization of D.C.Magnetron Sputtered Ti-Nb-N Thin Film Coatings on Stainless Steel[M]//Characterization of Minerals,Metals,and Materials 2016. [S.l.]: John Wiley & Sons, Ltd., 2016.
【12】 GRIMBERG I,ZHITOMIRSKY V M,BOXMAN R L,et al.Multicomponent Ti-Zr-N and Ti-Nb-N coatings deposited by vacuum arc[J].Surface and Coatings Technology,1998,108/109:154-159.
【13】 赵彦辉, 林国强, 董闯,等. 脉冲偏压电弧离子镀TiNbN硬质薄膜及结构多层薄膜的制各及性能[C]// TFC'05全国薄膜技术学术研讨会论文摘要集. 北京:中国真空学会,2005. ZHAO Y H, LIN G Q, DONG C, et al. Preparation and properties of TiNbN hard films and multilayer films by pulsed bias arc ion plating [C]// Proceedings of TFC'05 National Thin Film Technology Conference. Beijing: Chinese Vacuum Society, 2005.
【14】 徐重,张艳梅,张平则,等.双层辉光等离子表面冶金技术[J].热处理,2009,24(1):1-11. XU Z,ZHANG Y M,ZHANG P Z, et al.Double glow plasma surface metallurgy technology[J].Heat Treatment,2009,24(1):1-11.
【15】 张军,张磊,李国栋,等.化学气相沉积ZrB2涂层的微观形貌及晶粒择优生长[J].材料研究学报,2017,31(3):168-174. ZHANG J,ZHANG L,LI G D,et al.Micro-morphology and preferential growth of ZrB2 coating prepared by chemical vapor deposition[J].Chinese Journal of Materials Research,2017,31(3):168-174.
【16】 刘国怀,李天瑞,徐莽,等.累积叠轧TC4钛合金的组织演化与力学性能[J].金属学报,2017,53(9):1038-1046. LIU G H,LI T R,XU M,et al.Microstructural evolution and mechanical properties of TC4 titanium alloy during acculative roll bonding process[J].Acta Metallurgica Sinica,2017,53(9):1038-1046.
【17】 JONES M I,MCCOLL I R,GRANT D M.Effect of substrate preparation and deposition conditions on the preferred orientation of TiN coatings deposited by RF reactive sputtering[J].Surface and Coatings Technology,2000,132(2/3):143-151.
【18】 SU C Y,LU C T,HSIAO W T,et al.Evaluation of the microstructural and photocatalytic properties of aluminum-doped zinc oxide coatings deposited by plasma spraying[J].Thin Solid Films,2013,544:170-174.
【19】 HOGMARK S,JACOBSON S,LARSSON M.Design and evaluation of tribological coatings[J].Wear,2000,246(1/2):20-33.
【20】 CHEN Z,WU L Y L,CHWA E,et al.Scratch resistance of brittle thin films on compliant substrates[J].Materials Science and Engineering:A,2008,493(1/2):292-298.
【21】 丛凤岐.金属压力变形的粘着及熔体润滑剂[J].锻压机械,1997,32(6):5-7. CONG F Q.Adhesion in metalforming process and the melt lubricant[J].Metalforming Machinery,1997,32(6):5-7.
【22】 刘瑞堂,刘锦云.金属材料力学性能[M].哈尔滨:哈尔滨工业大学出版社,2015. LIU R T,LIU J Y.Metal material mechanics performance[M]. Harbin:Harbin Institute of Technology Press,2015.
【23】 陈康敏,王树奇,杨子润,等.钢的高温氧化磨损及氧化物膜的研究[J].摩擦学学报,2008,28(5):475-479. CHEN K M,WANG S Q,YANG Z R,et al.High temperature wear and oxide film of steels[J].Tribology,2008,28(5):475-479.
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